Porous Ni2P nanoflower supported on nickel foam as an efficient three-dimensional electrode for urea electro-oxidation in alkaline medium

Porous Ni₂P nanoflower supported on nickel foam (Ni₂P@Ni foam) electrodes are synthesized via a simple hydrothermal growth strategy accompanied with further phosphating treatment. The prepared electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM). Electro-catalytic performances towards urea electro-oxidation are tested by cyclic voltammetry (CV), chronoamperometry (CA) coupled with electrochemical impedance spectroscopy (EIS). By phosphating Ni(OH)₂ precursor, the final obtained Ni₂P@Ni foam electrode presents a porous Ni₂P nanoflower structure within abundant porosity, and so exposes a large amount of electro-catalytic active sites and electronic transmission channels to accelerate the interfacial reaction. Compared with Ni(OH)₂@Ni foam precursor, the Ni₂P@Ni foam catalyst exhibits more excellent electro-catalytic activity as well as lower onset oxidation potential. Remarkably, the Ni₂P@Ni foam catalyst reaches a peak current density of 750 mA cm^?2 with an onset oxidation potential of 0.24 V (vs. Ag/AgCl) accompanied by an excellent stability in 0.60 M urea with 5.00 M KOH solutions. Benefiting from the unique porous nanosheet structure, the as-synthesized Ni₂P@Ni foam catalyst performs a highly enhanced catalytic behavior for alkaline urea electro-oxidation, indicating that the material can be hopefully applied in direct urea fuel cells.     

Quantitatively exploring the relationship between eye movement and driving behavior under the effect of different complex diagrammatic guide signs

Complex diagrammatic guide signs (DGSs) are widely used. To study the influence of DGSs with different complexities on drivers’ cognition, four types     

Highly Thermotolerant Metal Halide Perovskite Solids

By virtue of their narrow emission bands, near-unity quantum yield, and low fabrication cost, metal halide perovskites hold great promise in numerous aspects of optoelectronic applications, including solid-state lighting, lasing, and displays. Despite such promise, the poor temperature tolerance and suboptimal quantum yield of the existing metal halide perovskites in their solid state have severely limited their practical applications. Here, a straightforward heterogeneous interfacial method to develop superior thermotolerant and highly emissive solid-state metal halide perovskites is reported and their use as long-lasting high-temperature and high-input-power durable solid-state light-emitting diodes is illustrated. It is found that the resultant materials can well maintain their superior quantum efficiency after heating at a temperature over 150 °C for up to 22 h. A white light-emitting diode (w-LED) constructed from the metal halide perovskite solid exhibits superior temperature sustainable lifetime over 1100 h. The w-LED also displays a highly durable high-power-driving capability, and its working current can go up to 300 mA. It is believed that such highly thermotolerant metal halide perovskites will unleash the possibility of a wide variety of high-power and high-temperature solid-state lighting, lasing, and display devices that have been limited by existing methods.     

镍基MOF电极材料物理超声改性及电化学性能

采用水热法合成了以4,4′-联苯二甲酸(BPDC)为配体的Ni-金属有机框架(MOF),利用低成本、无污染的物理超声法在不改变Ni-MOF晶体结构的前提下对其进行改性,使块状Ni-MOF表面产生孔隙,改善Ni-MOF表面微/纳米结构,提高其电化学性能。通过扫描电子显微镜(SEM)图、X射线衍射(XRD)谱、循环伏安(CV)曲线和恒电流充放电(GCD)曲线分析了改性前后Ni-MOF的微结构形貌和电化学性能。结果表明,经过超声处理后,Ni-MOF的比表面积从40.6 m^2·g^-1增加到65.8 m^2·g^-1,平均孔径从12 nm增加到22 nm。在0.5 A·g^-1电流密度下,超声处理后Ni-MOF电极比电容从420 F·g^-1增加到515 F·g^-1,提高了22.6%,电荷转移电阻明显降低,从25.11Ω降低到15.51Ω。因此,物理超声法可有效改善Ni-MOF表面微/纳米结构,提高其电化学性能。     

Reference Point Based Multi-Objective Optimization of Reservoir Operation: a Comparison of Three Algorithms

Traditional multi-objective evolutionary algorithms treat each objective equally and search randomly in all solution spaces without using preference information. This might reduce the search efficiency and quality of solutions preferred by decision makers, especially when solving problems with complicated properties or many objectives. Three reference point based algorithms which adopt preference information in optimization progress, e.g., R-NSGA-II, r-NSGA-II and g-NSGA-II, have been shown to be effective in finding more preferred solutions in theoretical test problems. However, more efforts are needed to test their effectiveness in real-world problems. This study conducts a comparison of the above three algorithms with a standard algorithm NSGA-II on a reservoir operation problem to demonstrate their performance in improving the search efficiency and quality of preferred solutions. Under the same calculation times of the objective functions, Pareto optimal solutions of the four algorithms are used in the empirical comparison in terms of the approximation to the preferred solutions. Three performance indicators are then adopted for further comparison. Results show that R-NSGA-II and r-NSGA-II can improve the search efficiency and quality of preferred solutions. The convergence and diversity of their solutions in the concerned region are better than NSGA-II, and the closeness degree to the reference point can be increased by 42.8%, and moreover the number of preferred solutions can be increased by more than 3 times when part of objectives are preferred. By contrast, g-NSGA-II shows worse performance. This study exhibits the performance of three reference point based algorithms and provides insights in algorithm selection for multi-objective reservoir optimization problems.

     

SCMA场景下的极化码编解码方案改进研究

极化码是目前唯一一种被证明可达到信道容量的编码方式,稀疏码分多址接入(Sparse Code Division Multiple Access,SCMA)可以提高频谱资源的利用率和接入系统的用户接入数量。为了提升SCMA与极化码的联合系统的误码率性能和译码时延,使联合系统的应用越来越广泛,提出了2种降低译码复杂度的方式:简化的左信息更新方式和剪枝译码算法。简化的左信息更新方式对于N=256,N=1024的极化码分别能降低37.6%和44.6%的存储资源占用数;剪枝译码算法在码率为0.5时能降低50%左右的计算复杂度。基于简化的SCAN算法改进了联合检测译码算法,在接收机采用外循环迭代的结构,引入了阻尼机制,选取最优的阻尼方式和最优阻尼值。仿真分析了所提联合检测译码算法与原有联合检测译码算法的误码率性能差异,外迭代接收机性能与内外双循环迭代的接收机性能相同,采用阻尼机制联合接收机的性能比无阻尼接收机的性能高0.8 dB左右,SJIDD的误帧率性能比保留宽度为32的SCLJDD的性能低0.7 dB左右,但能使接收机处理时延降至原来的1/4~1/8。     

螺旋线镀金薄膜磁控溅射设备的研制

本文详细介绍了用于螺旋线镀金薄膜的磁控溅射设备的研制过程。首先明确了该设备的研制难点,其次对设备的主要组成部分进行了详细的说明,针对设备的几个研制难点提出了解决方案,最后利用研制好的设备进行了膜厚均匀性分析实验。实验表明膜层均匀性良好,达到了预期要求,客户反馈良好。     

不同层面倾角下锦屏一级水电站左岸板岩坡体破坏模式及能量特征

为了合理分析锦屏一级水电站左岸坡体的变形,选取坡体板岩进行巴西劈裂试验,分别研究了不同层面倾角下不同饱水率板岩的力学特性及能量特征。结果表明,板岩的抗拉强度随层面倾角的不断增加先减小后增加,其最大降幅达82%;同一层面倾角下,随着饱水程度的增加,板岩抗拉强度逐渐降低,在层面倾角为45°时,抗拉强度从1.64MPa降至0.52MPa,降幅达68%;试样层面倾角0°~90°的破坏受饱水率的影响较小,主要由层面倾角控制,破坏特征分为岩石拉伸型破坏、层面剪切破坏、基质-层面互剪型破坏、层面张拉破坏四种模式;试样破坏的累积能量随饱水程度的增加而不断减小,在相同饱水程度下,累积能量随层面倾角的增大而逐渐减小,累积能量的增长速率与荷载比成非线性关系,在轴向荷载达40%~80%时增长最快。     

Discovery of the Tiancilactone Antibiotics by Genome Mining of Atypical Bacterial Type II Diterpene Synthases

Although genome mining has advanced the identification, discovery, and study of microbial natural products, the discovery of bacterial diterpenoids continues to lag behind. Herein, we report the identification of 66 putative producers of novel bacterial diterpenoids, and the discovery of the tiancilactone (TNL) family of antibiotics, by genome mining of type II diterpene synthases that do not possess the canonical DXDD motif. The TNLs, which are broad‐spectrum antibiotics with moderate activities, are produced by both Streptomyces sp. CB03234 and Streptomyces sp. CB03238 and feature a highly functionalized diterpenoid skeleton that is further decorated with chloroanthranilate and γ‐butyrolactone moieties. Genetic manipulation of the tnl gene cluster resulted in TNL congeners, which provided insights into their biosynthesis and structure–activity relationships. This work highlights the biosynthetic potential that bacteria possess to produce diterpenoids and should inspire continued efforts to discover terpenoid natural products from bacteria.